一、課程說明(Course Description)
<br>本課程先複習熱力學三大定律及各種熱力學函數，例如熱容量,entropy,焓及自由能
<br>等，從統計熱力學解釋entropy之微觀意義;熱力學函數的基本數學;介紹熱力學之平
<br>衡觀念及單元系統的相轉變o再討論氣體的混合，討論理想與真實溶液之性質，雙元
<br>相圖與自由能之關係，化學反應之平衡觀念，特別以固態材料系統為對象，探討其
<br>化學反應及相轉變所需考量之熱力學觀念o
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<br>二、指定用書(Text Books)
<br> "Introduction to the thermodynamics of materials",
<br>  D.R. Gaskell;  4th Ed., 2003
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<br>三、參考書籍(References)
<br> 1. R.A. Swalin,"Thermodynamics of Solids", 2nd ed., 1972
<br> 2. R.T. DeHoff:"Thermodynamics in Materials Science", 1993
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<br>四、教學方式(Teaching Method)
<br>    課堂講授,討論,考試
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<br>五、教學進度(Syllabus)
<br>第一週	Ch.1~8 Review of fundamental Thermodynamics(I):
<br>1.Scope of Materials Thermodynamics, 2.Laws of Thermodynamics, 3.Definitions of thermodynamic functions and some important parameters, 4.Variation of V, S, H, G as a function of T, P.
<br>第二週	Ch.1~8 Review of fundamental Thermodynamics(II):
<br>1.Calculation of S, H, G and S, H, G for temperature changes at constant P, 2.Application of Gibbs-Helmholtz Eq., Clapeyron Eq., Clausius-Clapeyron Eq, 3.G(T,P) for a single phase substance and two-phases equilibrium.
<br>第三週	Ch.1~8 Review of fundamental Thermodynamics(III):
<br>1.Thermodynamics of ideal and real gases, 2. Thermodynamics of mixing of ideal gases: definitions of partial molar quantities, calculations of Smix, Umix, Hmix, Gmix
<br>第四週	Ch.9 Behavior of solutions(I):
<br>1.Raoult’s law and Henry’s law, 2.Activity of a component in solution, 3.Gibbs-Duhem equation, 4.Relation between G and   of binary solution, 5.Relation between ai,and  ,GM, 6.Method of graphical determination of   from GM
<br>第五週	Ch.9 Behavior of solutions(II):
<br>1.Properties of ideal solution, 2.Nonideal solution, 3.Application of Gibbs-Duhem equation (1-2).
<br>第六週	Ch.9 Behavior of solutions(III):
<br>1.Apllication of Gibbs-Duhem equation(3), 2.Regular solution,3.Non-regular solution
<br>第七週	Ch.9 Behavior of solutions(IV):
<br>1.Quasi-chemical model of solutions, 2.Calculation examples.
<br>第八週	Ch.10 Binary phase Diagrams and GM (XB) curves(I):
<br>1.GM (XB) curve of a homogeneous solution, 2. GM (XB) curve of a regular solution, 3.Citerior for phase stability in regular solution.
<br>第九週	1.Mid-term exam, 2. Ch.10 Binary phase Diagrams and GM (XB) curves(II): Standard states and two-phases equilibrium. 
<br>第十週	Ch.10 Binary phase Diagrams and GM (XB) curves(III):
<br>1.Isomorphous phase diagram, 2.Binary phase diagrams with liquid and solid exhibiting regular solution, 
<br>第十一週	Ch.10 Binary phase Diagrams and GM (XB) curves(IV):
<br>1.Eutectic phase diagrams.2.Monotectic phase diagram, 3.Calculation examples.
<br>第十二週	Ch.11 Reactions involving gases(I):
<br>1.Reaction equilibrium in gas mixture and equilibrium constant, 2.Effect of temperature on Kp, 3.Effect of total pressure on Kp.
<br>第十三週	Ch.11 Reactions involving gases(II):
<br>1.Reaction equilibrium in SO2-SO3-O2 system, 2.To keep a constant pO2 through gas mixture of SO2/SO3, CO/CO2, H2/H2O. 
<br>第十四週	Ch.11 Reactions involving gases(III): Calculation examples.
<br>Ch.12 Reactions involving gases and pure condensed phases(I): 1.Reaction equilibrium in a system containing pure condensed phases and gas phases. 2.Variation of “Standard Gibbs free energy change” with T.
<br>第十五週	Ch.12 Reactions involving gases and pure condensed phases(II): 1.Ellingham Diagrams, 2.Stability of metals and metal-oxides.
<br>第十六週	Ch.12 Reactions involving gases and pure condensed phases(III): 1.Effect of phase transition, 2.Stability of oxides in H2/H2O gas mixtures. 3.Nomographic scale of H2/H2O
<br>第十七週	Ch.12 Reactions involving gases and pure condensed phases(IV): 1.Stability of oxides in CO/CO2 gas mixtures,.2.Upper limit of (pCO/pCO2) at a fixed T, 3.Calculation examples.
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<br>六、成績考核(Evaluation)
<br> * 小考(20%)+期中考(40%)+期末考(40%)
<br> * 依原始分數之統計分布,調整學期成績.
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<br>七、可連結之網頁位址
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