一、課程說明(Course Desc<x>ription)
<br>本課程先複習熱力學三大定律及各種熱力學函數，例如熱容量,entropy,焓及自由能等，從統計熱
<br>力學解釋entropy之微觀意義;熱力學函數的基本數學;介紹熱力學之平衡觀念及單元系統的相轉變.
<br>下學期討論氣體的混合，討論理想與真實溶液之性質，雙元相圖與自由能之關係，化學反應之平衡
<br>觀念，特別以固態材料系統為對象，探討其化學反應及相轉變所需考量之熱力學觀念o
<br>
<br>
<br>二、指定用書(Text Books)
<br> "Introduction to the thermodynamics of materials",
<br>  D.R. Gaskell;  5th Ed.
<br>
<br>
<br>三、參考書籍(References)
<br> 1. R.A. Swalin,"Thermodynamics of Solids", 2nd ed., 1972
<br> 2. R.T. DeHoff:"Thermodynamics in Materials Science", 2nd ed.2006
<br>
<br>
<br>四、教學方式(Teaching Method)
<br>    課堂講授,討論,考試
<br>
<br>
<br>五、教學進度(Syllabus)
<br>Chapter 9. Behavior of solutions:  
<br>9.1. Introduction 
<br>9.2. Raoult’s law and Henry’s law 
<br>9.3. The thermodynamic activity of a component in solution 
<br>9.4. The Gibbs-Duhem equation 
<br>9.5. The Gibbs free energy of formation of a solution 
<br>9.6. The properties of Raoultian ideal solutions 
<br>9.7. Nonideal solutions 
<br>9.8. Application of the Gibbs-Duhem relation to the determination of 
<br>activity 
<br>9.9. Regular solutions 
<br>9.10. A statistical model of solutions 
<br>9.11. Subregular solutions 
<br>9.12. Numerical examples 
<br>
<br>Chapter 10. Gibbs free energy composition and the phase diagrams of binary 
<br>systems:
<br>10.1. Introduction 
<br>10.2. Gibbs free energy and thermodynamic activity 
<br>10.3. The Gibbs free energy of formation of regular solutions 
<br>10.4. Criteria for phase stability in regular solutions 
<br>10.5. Liquid and solid standard states 
<br>10.6. Phase diagrams, Gibbs free energy, and thermodynamic activity 
<br>10.7. The phase diagrams of binary systems that exhibit regular solution 
<br>behavior in the liquid and solid states 
<br>10.8. Numerical examples 
<br>
<br>Chapter 11. Reaction involving gases:  
<br>11.1. Introduction 
<br>11.2. Reaction equilibrium in a gas mixture and the equilibrium constant 
<br>11.3. The effect of temperature on the equilibrium constant 
<br>11.4. The effect of pressure on the equilibrium constant 
<br>11.5. Reaction equilibrium as a compromise between enthalpy and entropy 
<br>11.6. Reaction equilibrium in the system SO2(g)-SO3(g)-O2(g) 
<br>11.7. Equilibrium in H2O-H2 and CO2-CO mixtures 
<br>11.8. Numerical examples 
<br>
<br>Chapter 12 Reactions involving pure condensed phases and a gaseous phase: 
<br>12.1. Introduction 
<br>12.2. Reaction equilibrium in a system containing pure condensed phases and 
<br>a gas phase 
<br>12.3. The variation of the standard Gibbs free energy change with 
<br>temperature 
<br>12.4. Ellingham Diagrams 
<br>12.5. The effect of phase transformations 
<br>12.6. The oxides of carbon 
<br>12.7. Graphical representation of equilibria in the system me<x>tal-carbon- 
<br>oxygen 
<br>12.8. Numerical examples 
<br>
<br>六、成績考核(Evaluation)
<br>* 小考(20%)+期中考(40%)+期末考(40%)
<br>* 依原始分數之統計分布,調整學期成績.
<br>
<br>
<br>
<br>
<br>