一、課程說明(Course Description)

本課程 除簡單介紹陶瓷材料之特性外,以Pauling's rules為基礎介紹陶瓷材料之基本結構,以
及各種結晶構造及玻璃之基本特性。並介紹各種偏離理想構造之缺陷,包括各種離子點缺陷、電子
缺陷、以及點缺陷和晶界間之交互作用;缺陷對材料性質之影響,尤其是物質與電性傳遞性質;陶
瓷材料之平衡相圖,特別是三元系統,以膫解陶瓷材料系統之熱力平衡及特性;以及影響陶瓷材料
微觀結構之因素,包括表面能、介面能、粒徑、粒徑分佈、粉末堆 積、溫度等重要參數,及其對性
質的影響。

二、指定用書(Text Books)

"Physical Ceramics : Principles for Ceramic Science and Engineering"
by Yet-Ming Chiang, Dunbar Birnie III, W. David Kingery


三、參考書籍(References):
"Fundamentals of Ceramics" by Michel Barsoum


四、教學方式(Teaching Method)

以投影片為主之互動式課堂講解。


五、教學進度(Syllabus)
Chapter 1. Structure of Ceramics :
1.1. Close-packed lattices
1.2. Stability of ionic crystals and Pauling’s rules
1.3. Ceramic crystal structures: fcc-based structures, hcp-based
structures,
perovskite, and spinel structures
1.4. Crystalline silicates
1.5. Glass strcture

Chapter 2.Defects in Ceramics :
2.1. Point defects: Intrinsic ionic disorder, Defect chemical reactions, extent
of nonstoichiometry, electronic disorder
2.2. Simultaneous defect equilibria, the Brouwer diagram
2.3. Defect association and precipitation
2.4. Interactions between point defects and interfaces

Chapter 3. Mass and Electrical Transport in ceramics :
3.1. Continuum diffusion kinetics
3.2. Atomic diffusion processes
3.3. Electrical conductivity
3.4. The electrochemical potential

Chapter 4. Phase Equilibria of Ceramics :
4.1. Thermodynamic equilibrium
4.2. The Gibbs phase rule
4.3. Binary phase diagrams
4.4. Features of ternary phase diagrams
4.5. Operations using ternary diagrams
4.6. Reactions upon heating and cooling

Chapter 5. Microstructure:
5.1. Capillarity
5.2. Grain growth and coarsening
5.3. Single phase sintering
5.4. Reactive additive sintering
5.5. Hot-pressing
5.6. Glasses and glass-ceramics

六、成績考核(Evaluation)
1.期中考 35%
2.期末考 35%
3.期末報告 30%