一、課程說明(Course Description)
本課程分兩學期授課,上學期先介紹熱力學三大定律及各種熱力學函數,例如熱容量,熵
(entropy),焓,及自由能等;並討論單相氣體及凝態系統之熱力學性質,從統計熱力學解釋,熵之
微
觀意義,以及partition function與自由能之關係式,並特別舉例說明其應用於熱容量之理論推
導o 本學期則討論理想與真實溶液之性質,雙元相圖與自由能之關係,化學反應之平衡觀念,特別
以
固態材料系統為對象,探討其化學反應及相轉變所需考量之熱力學。
二、指定用書(Text Books)
D.R. Gaskell: "Introduction to the Thermodynamics of Materials," 6th
ed.,2007.
三、參考書籍(References)
1.R.T. DeHoff, "Thermodynamics in Materials Science," McGraw-Hill, 1993.
2.R.A. Swalin, "Thermodynamics of Solids," 2nd ed., John Wiley&Sons, 1972.
四、教學方式(Teaching Method)
課堂講解及討論
五、教學進度(Syllabus)
Chapter 9. Behavior of solutions: (12小時)
9.1. Introduction
9.2. Raoult’s law and Henry’s law
9.3. The thermodynamic activity of a component in solution
9.4. The Gibbs-Duhem equation
9.5. The Gibbs free energy of formation of a solution
9.6. The properties of Raoultian ideal solutions
9.7. Nonideal solutions
9.8. Application of the Gibbs-Duhem relation to the determination of
activity
9.9. Regular solutions
9.10. A statistical model of solutions
9.11. Subregular solutions
9.12. Numerical examples

Chapter 10. Gibbs free energy composition and the phase diagrams of binary
systems: (12小時)
10.1. Introduction
10.2. Gibbs free energy and thermodynamic activity
10.3. The Gibbs free energy of formation of regular solutions
10.4. Criteria for phase stability in regular solutions
10.5. Liquid and solid standard states
10.6. Phase diagrams, Gibbs free energy, and thermodynamic activity
10.7. The phase diagrams of binary systems that exhibit regular solution
behavior in the liquid and solid states
10.8. Numerical examples

Chapter 11. Reaction involving gases: (9小時)
11.1. Introduction
11.2. Reaction equilibrium in a gas mixture and the equilibrium constant
11.3. The effect of temperature on the equilibrium constant
11.4. The effect of pressure on the equilibrium constant
11.5. Reaction equilibrium as a compromise between enthalpy and entropy
11.6. Reaction equilibrium in the system SO2(g)-SO3(g)-O2(g)
11.7. Equilibrium in H2O-H2 and CO2-CO mixtures
11.8. Numerical examples

Chapter 12 Reactions involving pure condensed phases and a gaseous phase: (9
小時)
12.1. Introduction
12.2. Reaction equilibrium in a system containing pure condensed phases and
a gas phase
12.3. The variation of the standard Gibbs free energy change with
temperature
12.4. Ellingham Diagrams
12.5. The effect of phase transformations
12.6. The oxides of carbon
12.7. Graphical representation of equilibria in the system metal-carbon-
oxygen
12.8. Numerical examples
六、成績考核(Evaluation)
1. 小考:30%
2. 期中考Ⅱ: 30%
3. 期末考 40%
4. 依原始分數之統計分布，調整學期成績。