1. Course description: The purpose of this course is to provide students
fundamental knowledge of essential kinetics of various material systems. The
subjects covered are (1) Diffusion; (2) Chemical reactions; (3) Phase
transformations.

2. Reference Book:
(1) R. W. Balluffi, "Kinetics of Materials", Wiley 2005
(2) O. Levenspiel, “Chemical Reaction Engineering”, 3rd Ed., John Wiley & Sons,
1999.
(3) D. A. Porter,“Phase Transformations in metals and alloys”, 2nd Ed.,
Chapman & Hall, 1992.

3. Teaching methods:
Lecture
Prerequisite courses: Engineering Mathematics, Thermodynamics, Physical
metallurgy
Grade: Quiz (30%), Midterm (35%), Final (35%)

4. Outlines:

Lecture 1 Introduction
Thermodynamics vs. Kinetics; steady flow process; irreversible thermodynamics;
entropy production & driving force
Lecture 2 Driving forces for mass transport
Chemical potential gradient; electric field; temperature gradient ; Surface
potential
gradient; Stress gradient
Lecture 3 Diffusion equations and solutions
Steady and non-steady solutions; Boltzmann-Matano analysis
Lecture 4 Diffusion mechanism
Thermally activated atomic jumping; atomic diffusion mechanism; diffusion in
ionic
solids
Lecture 5 Diffusion in crystal imperfections
Grain boundary diffusion; Surface diffusion ; Dislocation diffusion
Midterm Examination
Lecture 6 Homogeneous chemical reactions
Batch-type reaction; Rate equation & analysis methodology
Lecture 7 Hetergeneous chemical reactions
Fluid-solid; Fluid-Fluid; Fluid-Particle reactions
Lecture 8 Coarsening & grain growth
Lecture 9 Spinodal decomposition
Lecture 10 Nucleation theory
Lecture 11 Solidification
Final Examination
Lecture note download: http://www.mse.nthu.edu.tw/~cnliao/